Io is a prototype-based language. There are no classes and instances; there are only objects.
Objects are typically cloned (from Object or some other existing object) and then extended, i.e. attributes are added to it on the fly.
A typical idiom seems to be:
a := Object clone do( x := 42 foo := method(...) ...etc... )
The do method evaluates whatever is defined in its scope and adds it to the object. So the aforementioned code is the same as:
a = Object clone a x := 42 a foo := method(...)
TODO:
For Object and its methods, see here.